Try this:
CREATE TABLE #tmp ([Name] VARCHAR(300),[Value] VARCHAR(300))
INSERT INTO #tmp ([Name], [Value])
SELECT 'Employee_RefID', 'BF-006205'
UNION ALL SELECT 'Physical_Environment', '3'
UNION ALL SELECT 'TLM_DISPLAY', '4'
UNION ALL SELECT 'Emotional_Environment', '4'
UNION ALL SELECT 'Complete_Lesson_Plan', '4'
UNION ALL SELECT 'Use_of_Instructional_aids_technique', '4'
UNION ALL SELECT 'Open_ended_questioning', '4'
UNION ALL SELECT 'Active_listening', '4'
UNION ALL SELECT 'Student_talk_time', '4'
UNION ALL SELECT 'Creative_TLMs', '3'
UNION ALL SELECT 'Conduct_of_activity_based_teaching', '3'
UNION ALL SELECT 'Seating_arrangement', '3'
UNION ALL SELECT 'Effective_verbal_and_non_verbal_communication', '3'
UNION ALL SELECT 'Friendly_disposition_of_Teachers', '4'
UNION ALL SELECT 'Response_time_for_students_to_answer', '4'
UNION ALL SELECT 'Small_Group_Work', '3'
UNION ALL SELECT 'Maximizing_learning_time', '4'
UNION ALL SELECT 'Appropriate_TLM', '3'
UNION ALL SELECT 'Use_of_ICT', '3'
UNION ALL SELECT 'Organisation_of_hand_work', '2'
UNION ALL SELECT 'Appropriate_Opening', '3'
UNION ALL SELECT 'Suitable_Closing', '3'
UNION ALL SELECT 'Cooperation_of_Teacher', '4'
UNION ALL SELECT 'Courtesy_of_Teacher', '4'
UNION ALL SELECT 'Peer_assistance', '4'
UNION ALL SELECT 'Punctuality', '3'
UNION ALL SELECT 'Conduct', '4'
UNION ALL SELECT 'Grooming', '4'
UNION ALL SELECT 'Respect_for_Students_Peers', '4'
UNION ALL SELECT 'Respect_for_Community', '3'
UNION ALL SELECT 'Honesty_and_Integrity', '3'
UNION ALL SELECT 'Professional_dealing_with_parents', '3'
UNION ALL SELECT 'Helps_parents_understand_childs_needs_progress', '3'
UNION ALL SELECT 'Maintenance_of_records_proper_filling_of_MIS_economic_usage_of_stationery', '4'
UNION ALL SELECT 'Practicises_hygienic_behaviour', '3'
UNION ALL SELECT 'Encourages_Hygiene_behaviour_in_students', '3'
UNION ALL SELECT 'Uses_Computer_independently', '3'
UNION ALL SELECT 'Able_to_work_with_software_installed', '4'
UNION ALL SELECT 'Able_to_fill_up_computer_based_MIS_independently', '3'
UNION ALL SELECT 'Employee_RefID', 'BF-005196'
UNION ALL SELECT 'Physical_Environment', '3'
UNION ALL SELECT 'TLM_DISPLAY', '3'
UNION ALL SELECT 'Emotional_Environment', '4'
UNION ALL SELECT 'Complete_Lesson_Plan', '3'
UNION ALL SELECT 'Use_of_Instructional_aids_technique', '4'
UNION ALL SELECT 'Open_ended_questioning', '4'
UNION ALL SELECT 'Active_listening', '4'
UNION ALL SELECT 'Student_talk_time', '4'
UNION ALL SELECT 'Creative_TLMs', '3'
UNION ALL SELECT 'Conduct_of_activity_based_teaching', '3'
UNION ALL SELECT 'Seating_arrangement', '4'
UNION ALL SELECT 'Effective_verbal_and_non_verbal_communication', '4'
UNION ALL SELECT 'Friendly_disposition_of_Teachers', '4'
UNION ALL SELECT 'Response_time_for_students_to_answer', '3'
UNION ALL SELECT 'Small_Group_Work', '3'
UNION ALL SELECT 'Maximizing_learning_time', '4'
UNION ALL SELECT 'Appropriate_TLM', '3'
UNION ALL SELECT 'Use_of_ICT', '3'
UNION ALL SELECT 'Organisation_of_hand_work', '3'
UNION ALL SELECT 'Appropriate_Opening', '4'
UNION ALL SELECT 'Suitable_Closing', '4'
UNION ALL SELECT 'Cooperation_of_Teacher', '4'
UNION ALL SELECT 'Courtesy_of_Teacher', '3'
UNION ALL SELECT 'Peer_assistance', '4'
UNION ALL SELECT 'Punctuality', '4'
UNION ALL SELECT 'Conduct', '3'
UNION ALL SELECT 'Grooming', '4'
UNION ALL SELECT 'Respect_for_Students_Peers', '3'
UNION ALL SELECT 'Respect_for_Community', '4'
UNION ALL SELECT 'Honesty_and_Integrity', '4'
UNION ALL SELECT 'Professional_dealing_with_parents', '3'
UNION ALL SELECT 'Helps_parents_understand_childs_needs_progress', '3'
UNION ALL SELECT 'Maintenance_of_records_proper_filling_of_MIS_economic_usage_of_stationery', '4'
UNION ALL SELECT 'Practicises_hygienic_behaviour', '3'
UNION ALL SELECT 'Encourages_Hygiene_behaviour_in_students', '3'
UNION ALL SELECT 'Uses_Computer_independently', '4'
UNION ALL SELECT 'Able_to_work_with_software_installed', '3'
UNION ALL SELECT 'Able_to_fill_up_computer_based_MIS_independently', '3'
UNION ALL SELECT 'Employee_RefID', 'BF-005194'
UNION ALL SELECT 'Physical_Environment', '3'
UNION ALL SELECT 'TLM_DISPLAY', '4'
UNION ALL SELECT 'Emotional_Environment', '4'
UNION ALL SELECT 'Complete_Lesson_Plan', '3'
UNION ALL SELECT 'Use_of_Instructional_aids_technique', '3'
UNION ALL SELECT 'Open_ended_questioning', '4'
UNION ALL SELECT 'Active_listening', '4'
UNION ALL SELECT 'Student_talk_time', '4'
UNION ALL SELECT 'Creative_TLMs', '4'
UNION ALL SELECT 'Conduct_of_activity_based_teaching', '4'
UNION ALL SELECT 'Seating_arrangement', '3'
UNION ALL SELECT 'Effective_verbal_and_non_verbal_communication', '4'
UNION ALL SELECT 'Friendly_disposition_of_Teachers', '4'
UNION ALL SELECT 'Response_time_for_students_to_answer', '4'
UNION ALL SELECT 'Small_Group_Work', '3'
UNION ALL SELECT 'Maximizing_learning_time', '4'
UNION ALL SELECT 'Appropriate_TLM', '3'
UNION ALL SELECT 'Use_of_ICT', '3'
UNION ALL SELECT 'Organisation_of_hand_work', '3'
UNION ALL SELECT 'Appropriate_Opening', '3'
UNION ALL SELECT 'Suitable_Closing', '3'
UNION ALL SELECT 'Cooperation_of_Teacher', '4'
UNION ALL SELECT 'Courtesy_of_Teacher', '3'
UNION ALL SELECT 'Peer_assistance', '4'
UNION ALL SELECT 'Punctuality', '3'
UNION ALL SELECT 'Conduct', '3'
UNION ALL SELECT 'Grooming', '4'
UNION ALL SELECT 'Respect_for_Students_Peers', '3'
UNION ALL SELECT 'Respect_for_Community', '3'
UNION ALL SELECT 'Honesty_and_Integrity', '4'
UNION ALL SELECT 'Professional_dealing_with_parents', '4'
UNION ALL SELECT 'Helps_parents_understand_childs_needs_progress', '4'
UNION ALL SELECT 'Maintenance_of_records_proper_filling_of_MIS_economic_usage_of_stationery', '4'
UNION ALL SELECT 'Practicises_hygienic_behaviour', '3'
UNION ALL SELECT 'Encourages_Hygiene_behaviour_in_students', '3'
UNION ALL SELECT 'Uses_Computer_independently', '3'
UNION ALL SELECT 'Able_to_work_with_software_installed', '3'
UNION ALL SELECT 'Able_to_fill_up_computer_based_MIS_independently', '3'
UNION ALL SELECT 'Employee_RefID', 'BF-005913'
UNION ALL SELECT 'Physical_Environment', '3'
UNION ALL SELECT 'TLM_DISPLAY', '3'
UNION ALL SELECT 'Emotional_Environment', '3'
UNION ALL SELECT 'Complete_Lesson_Plan', '4'
UNION ALL SELECT 'Use_of_Instructional_aids_technique', '4'
UNION ALL SELECT 'Open_ended_questioning', '4'
UNION ALL SELECT 'Active_listening', '4'
UNION ALL SELECT 'Student_talk_time', '4'
UNION ALL SELECT 'Creative_TLMs', '3'
UNION ALL SELECT 'Conduct_of_activity_based_teaching', '2'
UNION ALL SELECT 'Seating_arrangement', '3'
UNION ALL SELECT 'Effective_verbal_and_non_verbal_communication', '4'
UNION ALL SELECT 'Friendly_disposition_of_Teachers', '2'
UNION ALL SELECT 'Response_time_for_students_to_answer', '3'
UNION ALL SELECT 'Small_Group_Work', '3'
UNION ALL SELECT 'Maximizing_learning_time', '3'
UNION ALL SELECT 'Appropriate_TLM', '4'
UNION ALL SELECT 'Use_of_ICT', '3'
UNION ALL SELECT 'Organisation_of_hand_work', '2'
UNION ALL SELECT 'Appropriate_Opening', '3'
UNION ALL SELECT 'Suitable_Closing', '3'
UNION ALL SELECT 'Cooperation_of_Teacher', '4'
UNION ALL SELECT 'Courtesy_of_Teacher', '4'
UNION ALL SELECT 'Peer_assistance', '3'
UNION ALL SELECT 'Punctuality', '4'
UNION ALL SELECT 'Conduct', '3'
UNION ALL SELECT 'Grooming', '3'
UNION ALL SELECT 'Respect_for_Students_Peers', '4'
UNION ALL SELECT 'Respect_for_Community', '4'
UNION ALL SELECT 'Honesty_and_Integrity', '3'
UNION ALL SELECT 'Professional_dealing_with_parents', '4'
UNION ALL SELECT 'Helps_parents_understand_childs_needs_progress', '3'
UNION ALL SELECT 'Maintenance_of_records_proper_filling_of_MIS_economic_usage_of_stationery', '4'
UNION ALL SELECT 'Practicises_hygienic_behaviour', '3'
UNION ALL SELECT 'Encourages_Hygiene_behaviour_in_students', '3'
UNION ALL SELECT 'Uses_Computer_independently', '3'
UNION ALL SELECT 'Able_to_work_with_software_installed', '3'
UNION ALL SELECT 'Able_to_fill_up_computer_based_MIS_independently', '3'
UNION ALL SELECT 'Employee_RefID', 'BF-006038'
UNION ALL SELECT 'Physical_Environment', '4'
UNION ALL SELECT 'TLM_DISPLAY', '4'
UNION ALL SELECT 'Emotional_Environment', '3'
UNION ALL SELECT 'Complete_Lesson_Plan', '3'
UNION ALL SELECT 'Use_of_Instructional_aids_technique', '3'
UNION ALL SELECT 'Open_ended_questioning', '4'
UNION ALL SELECT 'Active_listening', '4'
UNION ALL SELECT 'Student_talk_time', '4'
UNION ALL SELECT 'Creative_TLMs', '4'
UNION ALL SELECT 'Conduct_of_activity_based_teaching', '4'
UNION ALL SELECT 'Seating_arrangement', '3'
UNION ALL SELECT 'Effective_verbal_and_non_verbal_communication', '3'
UNION ALL SELECT 'Friendly_disposition_of_Teachers', '3'
UNION ALL SELECT 'Response_time_for_students_to_answer', '4'
UNION ALL SELECT 'Small_Group_Work', '4'
UNION ALL SELECT 'Maximizing_learning_time', '4'
UNION ALL SELECT 'Appropriate_TLM', '3'
UNION ALL SELECT 'Use_of_ICT', '3'
UNION ALL SELECT 'Organisation_of_hand_work', '2'
UNION ALL SELECT 'Appropriate_Opening', '4'
UNION ALL SELECT 'Suitable_Closing', '3'
UNION ALL SELECT 'Cooperation_of_Teacher', '4'
UNION ALL SELECT 'Courtesy_of_Teacher', '4'
UNION ALL SELECT 'Peer_assistance', '4'
UNION ALL SELECT 'Punctuality', '3'
UNION ALL SELECT 'Conduct', '3'
UNION ALL SELECT 'Grooming', '4'
UNION ALL SELECT 'Respect_for_Students_Peers', '3'
UNION ALL SELECT 'Respect_for_Community', '3'
UNION ALL SELECT 'Honesty_and_Integrity', '4'
UNION ALL SELECT 'Professional_dealing_with_parents', '3'
UNION ALL SELECT 'Helps_parents_understand_childs_needs_progress', '4'
UNION ALL SELECT 'Maintenance_of_records_proper_filling_of_MIS_economic_usage_of_stationery', '3'
UNION ALL SELECT 'Practicises_hygienic_behaviour', '3'
UNION ALL SELECT 'Encourages_Hygiene_behaviour_in_students', '4'
UNION ALL SELECT 'Uses_Computer_independently', '3'
UNION ALL SELECT 'Able_to_work_with_software_installed', '3'
UNION ALL SELECT 'Able_to_fill_up_computer_based_MIS_independently', '4'
UNION ALL SELECT 'Employee_RefID', 'BF-006039'
UNION ALL SELECT 'Physical_Environment', '3'
UNION ALL SELECT 'TLM_DISPLAY', '2'
UNION ALL SELECT 'Emotional_Environment', '4'
UNION ALL SELECT 'Complete_Lesson_Plan', '4'
UNION ALL SELECT 'Use_of_Instructional_aids_technique', '4'
UNION ALL SELECT 'Open_ended_questioning', '2'
UNION ALL SELECT 'Active_listening', '4'
UNION ALL SELECT 'Student_talk_time', '4'
UNION ALL SELECT 'Creative_TLMs', '2'
UNION ALL SELECT 'Conduct_of_activity_based_teaching', '4'
UNION ALL SELECT 'Seating_arrangement', '3'
UNION ALL SELECT 'Effective_verbal_and_non_verbal_communication', '4'
UNION ALL SELECT 'Friendly_disposition_of_Teachers', '3'
UNION ALL SELECT 'Response_time_for_students_to_answer', '3'
UNION ALL SELECT 'Small_Group_Work', '2'
UNION ALL SELECT 'Maximizing_learning_time', '2'
UNION ALL SELECT 'Appropriate_TLM', '4'
UNION ALL SELECT 'Use_of_ICT', '4'
UNION ALL SELECT 'Organisation_of_hand_work', '2'
UNION ALL SELECT 'Appropriate_Opening', '3'
UNION ALL SELECT 'Suitable_Closing', '3'
UNION ALL SELECT 'Cooperation_of_Teacher', '3'
UNION ALL SELECT 'Courtesy_of_Teacher', '4'
UNION ALL SELECT 'Peer_assistance', '4'
UNION ALL SELECT 'Punctuality', '4'
UNION ALL SELECT 'Conduct', '3'
UNION ALL SELECT 'Grooming', '3'
UNION ALL SELECT 'Respect_for_Students_Peers', '3'
UNION ALL SELECT 'Respect_for_Community', '4'
UNION ALL SELECT 'Honesty_and_Integrity', '3'
UNION ALL SELECT 'Professional_dealing_with_parents', '3'
UNION ALL SELECT 'Helps_parents_understand_childs_needs_progress', '4'
UNION ALL SELECT 'Maintenance_of_records_proper_filling_of_MIS_economic_usage_of_stationery', '4'
UNION ALL SELECT 'Practicises_hygienic_behaviour', '3'
UNION ALL SELECT 'Encourages_Hygiene_behaviour_in_students', '3'
UNION ALL SELECT 'Uses_Computer_independently', '4'
UNION ALL SELECT 'Able_to_work_with_software_installed', '3'
UNION ALL SELECT 'Able_to_fill_up_computer_based_MIS_independently', '4'
DECLARE @cols VARCHAR(6000)
SET @cols = STUFF((SELECT DISTINCT '],[' + [Name]
FROM #tmp
ORDER BY '],[' + [Name]
FOR XML PATH('')),1,2,'') + ']'
DECLARE @dt VARCHAR(8000)
DECLARE @pt VARCHAR(MAX)
SET @dt = N'SELECT *, ROW_NUMBER() OVER(PARTITION BY [Name] ORDER BY [Name]) AS RowID
FROM #tmp'
SET @pt = N'SELECT RowID, ' + @cols +
' FROM (' + @dt + ') AS DT' +
' PIVOT(MAX([VALUE]) FOR [Name] IN(' + @cols + ')) AS PT'
EXEC(@pt)
DROP TABLE #tmp