Double quotes delimit strings: "Hello World".
Single quotes delimit characters: 'H', 'e', 'l', ...
But the original problem was spelling ...
System.Diagonsis.Process.Start ( "C:/Users/Shark ...
Should be:
System.Diagnostics.Process.Start ( "C:/Users/Shark ...
However, that probably won't work, and almost certainly not in production: IIS doesn't run under your user, it has it's own with heavily restricted access to hard drives and related hardware. So that folder will not be accessible to your web based app.