Look at the error message:
File not found exception was unhandled
It's couldn;t be any clearer if it tried: the file you told it to load the image from does not exist.
We can't help you with that: we don't have any access to your file system, or any idea what path you are feeding to the method - and you need both to try and work out what the problem might be.
So, it's going to be up to you.
Fortunately, you have a tool available to you which will help you find out what is going on: the debugger. If you don't know how to use it then a quick Google for "Visual Studio debugger" should give you the info you need.
Put a breakpoint on the first line in the function, and run your code through the debugger. Then look at your code, and at your data and work out what should happen manually. Then single step each line checking that what you expected to happen is exactly what did. When it isn't, that's when you have a problem, and you can back-track (or run it again and look more closely) to find out why.
Sorry, but we can't do that for you - time for you to learn a new (and very, very useful) skill: debugging!