SELECT Amount, PaymentMode FROM DailyCash WHERE Company = 'Head Office';
SELECT Amount, PaymentMode FROM DailyCash WHERE Company = 'Branches';
But ... that's a very poor design. You shouldn't bew sorting "Company" or "PaymentMode" as strings: they should be in two separate tables each with an IDENTITY based ID column which you reference via a Foreign Key from your DailyCash table, via a JOIN.
Doing it your way both wastes space (strings are bigger than IDs) and encourages errors as the string field could be badly entered: 'Heed Office' or 'CEDIT CARD' for example.