Your code seems incomplete or dont know what you want to do.
dt.Rows[ctr]["Serial"]
In this code what is ctr, Rows is jagged array where first boundary is columnName/Id and second boundary is RowID/RownNumber so your code should be like -
dt.Rows[ColumnName/ID][RowID]
What are you trying to do with this code?
Regards
Rushi