Just Create this method and Call in Form Load event of the form in which you want to center align the text of title bar.
private void Center_Text()
{
Graphics g = this.CreateGraphics();
Double startingPoint = (this.Width / 2) - (g.MeasureString(this.Text.Trim(), this.Font).Width / 2);
Double widthOfASpace = g.MeasureString(" ", this.Font).Width;
String tmp = " ";
Double tmpWidth = 0;
while ((tmpWidth + widthOfASpace) < startingPoint)
{
tmp += " ";
tmpWidth += widthOfASpace;
}
this.Text = tmp + this.Text.Trim();
}