How to make a regex for two digits comma string like (1, 23, 45, 67), every couple of digit is between 1 and 95

What I would do would be to use the Split() function and then try to convert the array elements into integers, and then check the resulting values.

My VB is not what it was and I do not have an IDE at the moment, so there may be syntax or other errors in this sample.

Dim LadderValues as String[] = Ladder.Split(new Char [] {','});
For Each LadderElement As String In LadderValues
  Dim LadderValue as Integer = -1
  If Integer.TryParse(LadderElement, LadderValue) Then
    If ((LadderValue < 1 ) Or (LadderValue >95 )) Then
        ' Deal with value out of range
    End If
  Else
    ' This element is not an integer
  End If

RegEx is made to match patterns, match 1 or 2 digits is easy, but if you want to match from 0 to 95; it is possible, but more complicated.
It is often considered easier to match 1 or 2 digits, then have code to do specific checking.

Just a few interesting links to help building and debugging RegEx.
Here is a link to RegEx documentation:
perlre - perldoc.perl.org[^]
Here is links to tools to help build RegEx and debug them:
.NET Regex Tester - Regex Storm[^]
Expresso Regular Expression Tool[^]
RegExr: Learn, Build, & Test RegEx[^]
Online regex tester and debugger: PHP, PCRE, Python, Golang and JavaScript[^]
This one show you the RegEx as a nice graph which is really helpful to understand what is doing a RegEx: Debuggex: Online visual regex tester. JavaScript, Python, and PCRE.[^]
This site also show the Regex in a nice graph but can't test what match the RegEx: Regexper[^]