There's few ways to read xml. Please, follow the instruction from past answer:
Read xml node from give xml file[
^]
I prefer to use XDocument + Linq:
Dim xdoc As XDocument = XDocument.Load("C:\Users\supervisor\Documents\Visual Studio 2015\Projects\mdi\mdi\tameio3.xml")
Dim employees = xdoc.Descendants("employee").ToList()
For Each ele As XElement In employees
Console.WriteLine("{0} - {1}", ele.Name, ele.Value)
Next
Good luck!