Use below code. The reason is when we add using
ds.Tables.Add("111");
it is not able to add table ot ds at 0 and 1 index.
DataTable dt1 = new DataTable();
DataTable dt2 = new DataTable();
MySqlConnection conn = new MySqlConnection("SERVER=....");
MySqlDataAdapter ad;
DataSet ds = new DataSet();
ad = new MySqlDataAdapter("SELECT * FROM 111", conn);
ad.Fill(dt1);
ad = new MySqlDataAdapter("SELECT * FROM 222", conn);
ad.Fill(dt2);
ds.Tables.Add(dt1);
ds.Tables.Add(dt2);
datagridview1.DataSource = ds.Tables[0];
datagridview2.DataSource = ds.Tables[1];