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I want to use Microsoft.Office.Interopt.Word .
You can't. Office Interop is not supported in services and web applications. Office is not reentrant, which means unpredicatble things happen if you enter the Office code from two different requests at the same time.
Also, there are some functions that result in a dialog popping up on the users desktop. Well, is service and web applications, that dialog pops up on the server, waiting forever for a response that will never come.
Use one of the SDK's, like the OpenXML SDK, the ClosedXML SDK, of whatever else you want to do this. You're going to have to consult the documentation on the SDK you use to find out how to attach a file to a Word document.