You can't use Outlook to send an email from a WebServer. First, you have to have Office installed on the server, but don't bother doing this. None of the Office applications are supported in a server (non-interactive) environment as Office applications do not support multiple requests at the same time. A web server is an example of this.
Why are you not using the built in
mail classes[
^] in the .NET Framework to send an email?