Simplest solution is check is the string starts with "00" and if so remove them. If not, check for "0" and remove that:
Private Shared Function StripLeadingZeros(ByVal s As String) As String
If s.StartsWith("00") Then
s = s.Substring(2)
ElseIf s.StartsWith("0") Then
s = s.Substring(1)
End If
Return s
End Function