Here is an article to get you started on working with word documents:
Word document automation through .NET[
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And here is an article to get you started on Entity Framework with Winforms to round out what you need:
Entity Framework in WinForms[
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If you are looking for someone to do this for you, you are on the wrong site. If you have tried to do this, and are running into a specific problem, we would be more than happy to help.