use below code
Response.Clear();
Response.AddHeader("content-disposition", "attachment;filename=FileName.xls");
Response.Buffer = true;
Response.ContentType = "application/vnd.xls";
Response.Charset = "";
EnableViewState = false;
System.IO.StringWriter oStringWriter = new System.IO.StringWriter();
System.Web.UI.HtmlTextWriter oHtmlTextWriter = new System.Web.UI.HtmlTextWriter(oStringWriter);
ClearControls(grd);
GridView1.RenderControl(oHtmlTextWriter);
Response.Write(oStringWriter.ToString());
Response.End();