So I came up with this solution. Add int to select the column (k) in this case, then use i int + 1 to place it underneath the datagrid. Working 100% Yeh!
Thank for you suggestion thoung phoenix1167 :-)
int i = 0;
int j = 0;
int k = 2;
int l = 1;
for (i = 0; i <= dataGridView1.RowCount - 1; i++)
{
for (j = 0; j <= dataGridView1.ColumnCount - 1; j++)
{
DataGridViewCell cell = dataGridView1[j, i];
xlWorkSheet.Cells[i + 18, j + 1] = cell.Value;
xlWorkSheet.Cells[i + 18 + 1, k + 1] = label13.Text;
xlWorkSheet.Cells[i + 18 + 1, l + 1] = "Total:";
}
}