Try this:
string checkuser = "select count(*) from [Table] where Username='" + tbUsername.Text + "'";
[EDIT]
Also modify in Button1_Click Event:
string insertQuery = "insert into [Table] (Username,Email,Password,Country) values(@Uname,@Email,@Passowrd,@Country)";
And also I think you should go though:
How I Write SQL, Part 1: Naming Conventions[
^]
--Amy