Below is sample code
<html xmlns="http://www.w3.org/1999/xhtml" >
<head runat="server">
<title>Untitled Page</title>
</head>
<body>
<form id="form1" runat="server">
<div>
<asp:Button ID="Button1" runat="server" Text="Print" OnClientClick="window.print()" />
</div>
</form>
</body>
</html>