Do something like this. Im using oracle database here.
Imports System.Net
Imports Oracle.DataAccess.Client
Imports System.Configuration
Imports System.Data
Partial Class _Default
Inherits System.Web.UI.Page
Public conSMART As New Oracle.DataAccess.Client.OracleConnection
Protected Sub TextBox1_TextChanged(sender As Object, e As System.EventArgs) Handles TextBox1.TextChanged
conSMART.ConnectionString = "Data Source=LIVE_SMART;User ID=smart_dev;Password=yourpassword"
conSMART.Open()
Dim usrname As String
usrname = TextBox1.Text.ToString
Dim sqlclause As String
Dim da As OracleDataAdapter
sqlclause = "select password as pwd from yourtable where username ='" + usrname + "'"
da = New OracleDataAdapter(sqlclause, conSMART)
Dim ds As New DataSet
da.Fill(ds)
TextBox2.Text = CType(ds.Tables(0).Rows(0)("pwd"), String)
End Sub