If you know the id of the captcha element for a certain website you can get it's src attribute and download from the url.
Here is an example of a captcha img in a div tag with the id "recaptcha_image".
<div id="recaptcha_image" style="width: 300px; height: 57px; "><img style="display:block;" alt="reCAPTCHA challenge image" height="57" width="300" src="http://www.google.com/recaptcha/api/image?c=03AHJ_Vus407GuhxqGfVSZawlQp2afR8Ov0GI0zpZolxeHbjXa5dRThbO0XWzAduWq5P7JNzA99oGPLSjuWQtnKotfv4Jy0EwkXBZv9kj9531F6YEwSop56pRTh4hOsWnO7n-CxLtH_w4pKC6OpRdw3KZZOXjgts3-Dg"></img></div>
Here is an example of how to get the image with a windows forms browser:
HtmlElement ele = browser.Document.GetElementById("recaptcha_image");
if (ele != null)
{
string imageSource = ele.GetAttribute("src");
}