Don't use manual authentication in ASP.net unless you have a really good reason to. Look at the Membership and Roles features and use them.
If you want to check for session expiry and auto-redirect then you need a little AJAX script that calls a server-side script that looks something like
Response.Write(null == Session["PassWord"] ? "expired" : "valid");
... and then checks the result and redirects to a login page if necessary.