I have solve this in different way.
protected void FillDdlSession()
{
SqlCommand cmd = new SqlCommand("SELECT DISTINCT session FROM quizResult ORDER BY session ASC", vcon);
SqlDataAdapter adp = new SqlDataAdapter(cmd);
DataTable dt = new DataTable();
adp.Fill(dt);
ddlSession.DataSource = dt;
ddlSession.DataTextField = "session";
ddlSession.DataValueField = "session";
ddlSession.DataBind();
ddlSession.Items.Insert(0, "Choose Session");
}