add a templated field to that grid view with checkbox control
eg->
<asp:TemplateField>
<ItemTemplate>
<asp:CheckBox ID="cb1" runat="server" />
</ItemTemplate>
</asp:TemplateField>
I'm providing the following example to retrieve the corresponding values where check boxes are checked
protected void Button1_Click(object sender, EventArgs e)
{
int sum = 0;
for (int i = 0; i < GridView1.Rows.Count; i++)
{
CheckBox cb = GridView1.Rows[i].FindControl("cb1") as CheckBox;
if (cb.Checked)
{
sum += Convert.ToInt32(GridView1.Rows[i].Cells[2].Text);
}
}
Label1.Text = sum.ToString();
}