the implementation with smartcard is in C# i.e reading and writing files from smartcard and card insertion or removal handler -> From what I can see here is the smartcard will contact / exchange date on some devices (card insertion / removal handler).
You need to implement on card insertion / removal handler as middle man in order to connect / exchange data with your PHP website. From c# you can create some web request to your PHP site.
some example here :
WebRequest objRequest = HttpWebRequest.Create("https://targetwebsitephp.com");
objRequest.Credentials = CredentialCache.DefaultNetworkCredentials;
objRequest.Proxy = WebRequest.DefaultWebProxy;
objRequest.Proxy.Credentials = CredentialCache.DefaultCredentials;
objRequest.UseDefaultCredentials = true;
WebResponse objResponse = (WebResponse)objRequest.GetResponse();
using (StreamReader sr = new StreamReader(objResponse.GetResponseStream()))
{
string str = sr.ReadToEnd();
sr.Close();
}
Maybe you can give us more info regarding your planning with your system.