You need to check that num2 is not zero before dividing.
This has nothing to do with your original question but will generate a divide by zero error if the user enters 0 for the 2nd number and "/" for the operation (try it!). Your code should be:
else if (op == "/") && (num2 != 0.0)
instead of
else if (op == "/")
You should always check that the denominator is not zero before dividing unless your calculation somehow assures that it cannot possibly be zero under any circumstances.