Just use intellisense: if you don't have it enabled by default, just type the first bit:
TimeSpan ts = new TimeSpan(
And use CTRL+SHIFT+SPACE to bring it up. It'll show you each of the possible parameter sets you can call it with (5 in this case) with their names - but you only need the names if you must use
name:value
syntax to provide them "out of order".
TimeSpan ts = new TimeSpan(hours:0, minutes:10, seconds:0)
is the same as saying
TimeSpan ts = new TimeSpan(0, 10, 0)
as the parameters are supplied in the order shown by intellisense: hours first, then minutes, then seconds.